Munson Hill Station is located off of Old Austinburg Road, just south of the intersection of Munson Hill Road and Ashtabula–Austinburg Road in Saybrook Township. The intersection of Munson Hill and Austinburg Road is approximately 1.5 miles east of OH-45.

The Western Reserve Greenway travels 43 miles through a scenic, mostly rural area, cutting a north-south course from Ashtabula to Warren in northeastern Ohio. The route follows much of the Pennsylvania Railroad’s former branch line, extending to the shores of Lake Erie at Ashtabula. This rail line once transported iron ore to the steel mills of eastern Ohio and western Pennsylvania. Today, the trail is the longest section of the planned 110-mile Great Ohio Lake-to-River Greenway that will begin on the shores of Lake Erie and travel south to the banks of the Ohio River in East Liverpool.